1 北京中材人工晶体研究院有限公司，北京100018
2 中材人工晶体研究院有限公司，北京100018
3 宁波大学物理科学与技术学院，高压物理科学研究院，宁波315211
4 中材人工晶体研究院(山东)有限公司，济南250200
采用物理气相传输(PVT)法通过同质外延生长获得14 mm×12 mm的AlN单晶样品。对样品进行切割、研磨、化学机械抛光处理后，采用拉曼光谱仪、高分辨X射线衍射仪、X射线光电子能谱仪、光致发光光谱仪对样品进行测试表征。拉曼测试结果表明，晶体中心区域的拉曼光谱E2(high)声子模的半峰全宽为3.3 cm-1，边缘区域E2(high)声子模的半峰全宽为4.3 cm-1，晶体呈现较高的结晶质量。XRD摇摆曲线表征结果显示，外延生长后的晶体中心和边缘区域的摇摆曲线半峰全宽增大至100″和205″，表明晶体内存在缺陷。XPS测试结果表明，晶体内存在C、O、Si杂质元素，杂质的原子数分数分别为0.74%、1.43%、2.14%，晶体内发现以氧杂质为主的Al—O、N—Al—O等特征峰。光致发光光谱测试结果显示，晶体内存在VAlON复合缺陷和VAl点缺陷。
氮化铝 物理气相传输法 半峰全宽 杂质 缺陷 AlN physical vapor transport method FWHM impurity defect
1 中材人工晶体研究院(山东)有限公司，济南250200
2 北京中材人工晶体研究院有限公司，北京100018
3 中材高新材料股份有限公司，北京100021
SiC是新一代射频器件和功率器件的理想材料，电阻式物理气相传输法由于具有温度均匀性，成为生长大尺寸SiC单晶的有效方法。近年来，多孔石墨等的使用提高了SiC晶体的质量和产量，而关于其机理的研究却相对较少。本文使用数值模拟的方法系统研究了多孔石墨对SiC晶体生长的影响，并进行了晶体生长验证。模拟结果表明：多孔石墨的使用提高了原料区域的温度及温度均匀性，增大了坩埚内轴向温差，对减弱原料表层的重结晶也具有一定作用；在生长腔内，多孔石墨改善了物质流动在整个生长过程中的稳定性，提高了生长区域的C/Si比，有助于减小相变发生概率，同时多孔石墨对晶体界面也起到改善作用。晶体生长结果实际验证了多孔石墨在提高传质均匀性、降低相变发生率和改善晶体外形上的作用。本文结果对于理解多孔石墨的作用机理以及改善SiC晶体生长条件具有实际意义。
碳化硅 多孔石墨 数值模拟 晶体生长 电阻加热 物理气相传输 silicon carbide porous graphite numerical simulation crystal growth resistance heating physical vapor transport
1 1.中国科学院 上海硅酸盐研究所, 高性能陶瓷和超微结构国家重点实验室, 上海 200050
2 2.中国科学院 上海硅酸盐研究所, 中试基地, 上海 201800
氧化物陶瓷纤维具有优良的耐高温和抗氧化性能, 是航空航天领域用复合材料增强相的重要候选材料。高温拉伸性能是氧化物陶瓷纤维在极端环境应用的关键评价指标之一, 但相关报道较少。本工作研究了国产550级纤维的高温拉伸性能和热处理后的室温拉伸性能, 探讨了纤维的拉伸性能与其物相和显微结构的演变关系和内在机理, 并与Nextel 720和CeraFib纤维的高温拉伸性能进行了对比。结果表明, 国产SIC550纤维复丝和单丝在1100 ℃以下具有相对较高的拉伸强度和拉伸强度保持率, 由于纤维中无定形SiO2的高温热稳定性较差, 对纤维1200 ℃以上的高温拉伸性能产生明显不利的影响; 通过在临界相转变温度(1300 ℃)对纤维进行热处理来形成莫来石相, 可在一定程度上改善纤维在1250~1400 ℃的高温拉伸性能。考虑到不同标距的影响, SIC550纤维在1100 ℃的高温拉伸强度(883 MPa)与Nextel 720 (1000 MPa)和CeraFib纤维(940 MPa)接近。
氧化铝 陶瓷纤维 高温拉伸性能 莫来石 alumina ceramic fiber high temperature tensile property mullite 
Author Affiliations
Abstract
1 Department of Optoelectronics Science, Harbin Institute of Technology at Weihai, Weihai 264209, China
2 School of Computer and Information, Hefei University of Technology, Hefei 230009, China
3 e-mail: slqu@hit.edu.cn
An ultrathin, planar, broadband metalens composed of metal rectangular split-ring resonators (MRSRRs) has been designed, which shows dual-polarity characteristics for different types of circularly polarized (CP) light incidence. The designed metalens can be considered as the focusing lens and the diverging lens under left-handed CP and right-handed CP light incidence, respectively. The phase discontinuity of the cross-polarized transmission light is produced by optical-axis rotation through modulating two arms’ lengths of the MRSRR. The MRSRR metalens possesses a wavelength-controllable focal length and a relatively larger chromatic aberration compared with the conventional lenses. And the focal length changes from 9 to 7 μm with incident wavelength from 740 to 950 nm. The dual-polarity flat metalens opens a door for new applications of phase discontinuity devices, and it will promote the fabricating capability of on-chip or fiber-embedded optical devices.
Lenses Metamaterials Phase modulation Photonics Research
2015, 3(3): 03000068
Author Affiliations
Abstract
1 School of Computer and Information, Hefei University of Technology, Hefei 230009, China
2 Department of Optoelectronics Science, Harbin Institute of Technology at Weihai, Weihai 264209, China
3 3Department of Physics, Harbin Institute of Technology, Harbin 150001, China
4 Department of Physics, Harbin Institute of Technology, Harbin 150001, China
In this paper, an ultrathin metalens has been proposed based on a holographic metasurface that consists of elongated apertures in 40 nm gold film, which exhibit intriguing properties such as on- and off-axis focusing and also can concentrate light into multiple, discrete spots for circularly polarized incident lights. First, the spatial transmission phase distributions of the designed metalens with arbitrary focusing can be obtained by computergenerated holography. Then, the discrete phase distributions can be continuously encoded by subwavelength nanoapertures with spatially varying orientations in gold film. The simulation results show that our designed metalens can work efficiently for different types of focusing. Finally, our metasurface shows superior broadband characteristics between 670 and 810 nm, and the corresponding focal lengths of the designed lenses also can be efficiently modulated with the incident lights at different wavelengths.
Metamaterials Metamaterials Optical devices Optical devices Phase modulation Phase modulation Optical resonators Optical resonators Photonics Research
2015, 3(5): 05000252
